BIOADSORPSI Fe(II) OLEH KULIT BUAH JERUK Citrus nobilis Lour. var microcarpa TERMODIFIKASI Ca(OH)2
DOI:
https://doi.org/10.26418/indonesian.v1i3.34205Abstract
Pontianak peel fruit waste contains pectin, cellulose, and hemicellulose which can be used as heavy metal adsorbents by modifying using Ca(OH)2. The purpose of this study was to determine the physicochemical characteristics of calcium-modified Pontianak Citrus adsorbents (JeP-Oca), determine the maximum capacity of Fe(II) adsorption by JeP-OCa, and JeP-OCa adsorption kinetics. The characteristics of the adsorbent were analyzed using the Fourier Transformation Infra Red (FTIR) showing the functional groups of "“OH and -COOH, Electron Scanning (SEM) Microscopy showing the surface structure of the canal and many irregular niches. The adsorption isotherm method with the BET model showed a large difference in porous surface area, namely 104.872 m2/g for JeP, 242.649 m2/g for JeP-ONa and 3759.745 m2/g for JeP-OCa. Optimization of the influence of pH, adsorbent mass, adsorbate concentration, and time using the column method. Adsorption isotherm followed the Freundlich isotherm model with maximum adsorption capacity value of 22.7272 mg/g. Fulfill the pseudo-order 2 reaction kinetics with a rate constant value of 4.097 L/mg. Min. The adsorption application using groundwater resulted in absorption efficiency of 82.99%.References
[[1] Ignasius D.A. Sutapa,LIPI, Kajian Jar Test Koagulasi Flokulasi Sebagai Dasar Perancangan Instalasipengolahan Air Gambut (Ipag) Menjadi Air Bersih
Kepmenkes, 1990, Peraturan Menteri Kesehatan Republik Indonesia No. 416/MENKES/PER/IX/1990 tentang Syarat-syarat dan Pengawasan Kualitas Air, Menteri Kesehatan Republik Indonesia, Jakarta
Darmono., 2001, Lingkungan Hidup dan Pencemaran, Jakarta: Universitas Indonesia Press
Agmalini, S. 2013. Peningkatan Kualitas Air Rawa Menggunakan Membran Keramik Berbahan Tanah Liat Alam dan Abu terbang batubara. Jurnal Teknik Kimia No. 2, Vol. 19.
Suherman, D. dan Nyoman Sumawijaya 2013, Menghilangkan Warna dan Zat Organik Air Gambut dengan Metode Koagulasi-Flokulasi Suasana Basa. Vol. 23, No.2, 127-139.
Puspita, U. dkk., ,2011, Kemampuan Tumbuhan Air sebagai Agen Fitoremediator logam Berat Kromium (Cr) yang Terdapat pada Limbah Cair Industri Batik. Jurnal Volume 39 no. 1.
Xing G-x, Zhang S-f, Ju B-z, Yan J-z. 2006, Study on adsorption behavior of cross linked cationic star chmaleate for chromium(VI). Carbohydr.Polym. 66.246-25.
Badan Pusat Statistik. 2010. Data produksi jeruk pontianak 2005-2010. BPS Kabupaten Sambas. Kalimantan Barat.
Wilkins MR, Widmer WW, Grohmann K. 2007, Simultane ous saccharification and fermentation of citrus peel waste by Saccharomyces cerevisiae to produce ethanol. Process Biochem. 42. 1614–1619.
Mamma D, Kourtoglou E, Christakopoulos P. 2008. Fungal multienzyme production on industrial by-products of the citrus-processing industry. Bioresour. Technol. 99. 2373–2383.
Shan W, Fang D, Zhao Z, Shuang Y, Ning L, Xing Z, Xiong Y. (2012). Aplication of orange peel for adsorption separation of molybdenum (VI) from recontaining industrial effluent, Biomass and Bioenergy. 37, 289-297.
Buchari, Toha,2010. Optimasi Proses Saponifikasi Kulit Jeruk Dengan Ca(OH)2 Dan Di Aktivasi Zirkonium Untuk Adsorben Ion Arsenik Dan Fosfor. Teknik Kimia,Universitas Brawijaya.
Vinisyanty I. 2013, Kajian Adsorbsi Pb(II) dengan Adsorben Limbah Jeruk Tersaponifikasi Ca(OH)2 dan NaOH. (tesis), Universitas Gadjah Mada, Yogyakarta.
Sulihono, A. 2012, Pengaruh Waktu, Temperatur, dan Jenis pelarut terhadap Ekstraksi Pektin dari Kulit Jeruk Bali (Citrus maxcima). Jurusan Teknik Kimia Fakultas Teknik Universitas Sriwijaya, Vol 18 no 4.
Lasheen .R dkk., 2012, Adsorption/Desorption Of Cd(II), Cu(II) And Pb(II) Using Chemically Modifiedorange Peel: Equilibrium And Kinetic Studies Solid State Sciences 14 (2012) 202e210.
Feng dkk.,2010, Enhanced Cu(II) Adsorption By Orange Peel Modified With Sodium Hydroxide, Science Press s146-s152
Nur Fitria Nella Wati, 2014. Peningkatan Kualitas Minyak Nilam Melalui Proses Adsorpsi Menggunakan Adsorben ï§ Alumina Dengan Sistem Flow. Indonesian Journal of Chemical Research Using Bios, Volume 1.
Igwe, JC., Abia, AA, 2006. Abioseparation Process for Removing Heavy Metals from Waste Water Using Biosorbents, African Journal of Biotechnology, 5.
Guo, dkk., 2010, Isotherm, Kinetik and Thermodynamic Studies of Adsorption of Cu2+ from Aqueous Solution by Mg2+/ K+ Type orange Peel Adsorbent,National Natural Science Foundation.
Putra A. dan Fitri W., 2016, KARAKTERISASI Pertukaran Ion Timbal (II) dengan Kalsium pada Proses Biosorpsi Alga Hijau Cladophora fracta, Jurnal Iptek Terapan Vol. 8 Hal 103-111.
Griffin. B,dkk., 1991 Environmental Scanning Electron Microscopic Study Of Macrophages Associated With The Tunica Vasculosa Lentis In The Developing Rat Eye.Britis Journal of Ophthalmology.
Suryaningtyas dkk., 2014, Kemampuan Pektin Kulit Jeruk Manis (Citrus sinensis) sebagai Biosorben Logam Berat krom (VI), Fakultas Teknobiologi, Universitas Atma Jaya Yogyakarta
Suziyana 2017, Pengaruh Massa Adsorben Batang Pisang dan Waktu Kontak Adsorpsi Terhadap Efisiensi Penyisihan Fe dan Kapasitas Adsorpsi Pada Pengolahan Air Gambut. Jom FTEKNIK Volume 4 No.1
Irawan C., dkk., 2015, Pengaruh Massa Adsorben, Lama Kontak Dan Aktivasi Adsorben Menggunakan HCl Terhadap Efektivitas Penurunan Logam Berat (Fe)Dengan Menggunakan Abu Layang Sebagai Adsorben. Jurnal Teknologi Terpadu Vol. 3 No. 2.
Ho, Y.S. dan G. McKay.1997, Pseudo-second order model for sorption processes Process Biochemistry 34 (1999) 451–46.
Fransina E.G dan Tanasale Matheis F.J.D.P, 2007. Studi Kinetika Adsoorpsi Biru Metilen pada Kitin dan Kitosan. J. Sains MIPA. Vol. 13 No. 3 Hap.171-176.
Atkins, P.W. 1990. Kimia Fisika Jilid 2 Edisi Keempat. Penerbit Erlangga. Jakarta.
Rosen, M. J. (1989). Surfactants and Interfacial Phenomena. New York, John Willey&Sons.
Hartati.I, dkk, 2011, Potensi Xanthate Pulpa Kopi Sebagai Adsorben Pada Pemisahan Ion Timbal Dari Limbah Industri Batik. Momentum, Vol. 7, No. 2, Oktober 2011 : 25- 30
Ali, S., 2015, Biosorpsi Ion Logam Cu (II) oleh Kulit Buah Naga (Hylocereus polyrhizus), (Skripsi), Universitas Hasanuddin, Makassar.
Effendi, H., 2007, Teknik Kualitas Air: bagi Pengolahan Sumber Daya dan Lingkungan Perairan, Yogyakarta: Kanisius.
Sari, D.R., Destiarti, L. & Wahyuni, N., 2014), Sintesis Pasir Kuarsa Terlapis mangan Dioksida dan Optimasi pH dalam Menurunkan Kadar Besi pada Tanah, Jurnal Kimia Khatulistiwa, 3(4), pp.26-31.
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