SINTESIS DAN KARAKTERISASI MOLECULARLY IMPRINTED POLYMERS MENGGUNAKAN METIL METAKRILAT DAN ETILEN GLIKOL DIMETAKRILAT SEBAGAI ADSORBEN DI-(2-ETILHEKSIL) FTALAT (SYNTHESIS AND CHARACTERIZATION OF MOLECULARLY IMPRINTED POLYMERS USING METHYL METHACRYLATE AND ETHYLENE GLYCOL DIMETACRILATE AS ADSORBENT DI-(2-ETILHEKSIL) PHTHALATE)
DOI:
https://doi.org/10.26418/indonesian.v5i3.59132Abstract
Molecularly Imprinted Polymer (MIP) is an intelligent synthetic material because it has the ability to selectively recognize target molecules. This study aims to synthesize, characterize and analyze the performance of MIP. MIP material was synthesized using di-(2-Ethylhexyl) phthalate (DEHP) as a template molecule, methyl methacrylate (MMA) monomer combined with ethylene glycol dimethacrylate (EGDMA) as a crosslinker by precipitation polymerization method. MIP materials were characterized by SEM-EDS instrument, FTIR spectrometer, SAA instrument, and UV-Vis spectrophotometer. The test variables for the adsorption ability of MIP material on DEHP compounds were time and concentration. The results showed that the synthesized MIP was in the form of a coarse white solid with a stiff texture. Characterization with the EDS instrument showed a decrease in the mass percent of C and percent of C atoms which indicated the formation of MIP_DEHP_MMA-co-EGDMA(TE) and the surface morphology characterized by the SEM instrument was composed of small grains that tend to be uniform and have pores. The bonds that affect the formation of polymers characterized by FTIR were "“C=C, "“C=O, and "“CO. Characterization with the SAA instrument was 142,2770 m2/g, the total pore volume was 0,2616 cm3/g and the average pore radius was 7.3562 nm, indicating mesoporous material. The optimum time for adsorption of MIP_DEHP_MMA-co-EGDMA(TE) to DEHP was 120 minutes. MIP_DEHP_MMA-co-EGDMA(TE) followed the pseudo-second-order kinetics model and the adsorption obeyed the Freundlich adsorption isothermReferences
Ilmiawati, C., Reza, M., Rahmatini., dan Rustam, E., (2017), Edukasi Pemakaian Plastik Sebagai Kemasan Makanan dan Minuman serta Risikonya Terhadap Kesehatan pada Komunitas di Kecamatan Bungus Teluk Kabung, Padang, Jurnal Kedokteran Universitas Andalas, 1(1): 1-8.
Amin, F., Rohaeti, E., dan Rafi, M, 2018, (Evaluation of Migrasi-(2-Etylheksil) Ftalat from Polyetylena Botle Terefalat Using GC/MS), Jurnal Itekima,3(1): 2548-947x.
ECPI, 2009, European Council for Plasticisers and Intermediate About DEHP, Luxemburg: Official Publication for the European Communities.
Yalkowsky, S.H., dan He, Y., 2003, Handbook of Aqueous Solubility Data, CRC Press, New York.
Safitri, A., 2011, Kontroversi Antimoni Trioksida, Universitas Paramadina, Jakarta.
Hennion, M.C. (1999). Review: Solid-phase extraction: method development, sorbents, and coupling with liquid chromatography. Journal of Chromatography A, 856: 3–54
Yang, Y., Jianlong, Y., Jie, Y., Bing, S., dan Jing, Z., 2014, Molecularly Imprinted Solid-Phase Extraction for Selective Extraction of Bisphenol Analogues in Bevarages and Canned Food, Journal of Agricultural & Food Chemistry, 62: 11130-11137.
Vasapollo,G., et al. 2011. Molecularly Imprinted Polymers: Present and Future Prospective. Int. J. Mol.Sci, 12: 5908-5945
Hidayat, A.R., dan Sunarto, 2017, Aplikasi MIP (Molecularly Imprinted Polymer) dengan Metanol sebagai Ekstraktan Template dalam Sintesisnya untuk Penentuan Kadar Kafein, Jurnal Kmia Dasar, 6: 45-52.
Freitas, A.F.F.L., 2015, Synthesis and Characterization of Molecularly Imprinted Polymer Particles (MIPs) for Biomedical Applications, Escola Superior de Tecnologia e Gestao, 1: 5-13.
Caro, E., Marce, R.M., Borrul, F., Cormack, P.A.G., dan Sherrington, D.C., 2006, Application of Molecularly Imprinted Polymer to Solid-Phase Extraction of Compounds from Environmental and Biological Samples, Trends in Analytical Chemistry, 25: 143-154.
Shaikh, H., Memon, N ., Khan, H., Bhanger, M.I., dan Nizamani, S.M., 2012, Preparation and Characterization of Molecularly Imprinted Polymer for Di(2- Ethylhexyl)Phthalate: Application to Sample Clean-Up Prior to Gas Chromatographic Determination, Journal of Chromatography A, 1247: 125- 133.
Yan, H., dan Row, K.H., 2006, Characteristic and Synthetic Approach of Molecularly Imprinted Polymer, International Journal of Molecule Science, 7: 155-178.
Adumitrachioaie, A., Tertis M., Cernat A., Sandulescu R., dan Cristea C., 2018, Electrochemical Methods Based on Molecularly Imprinted Polymers for Drug Detection, International Jurnal of Elektrochemical Science, 13: 2558-2562.
Hasanah, A.N., Utari, T.N.D., dan Pratiwi, R., 2019, Synthesis of Atenolol-Imprinted Polymers with Methyl Methacrylate as Functional Monomer in Propanol Using Bulk and Precipitation Polymerization Method, Journal of Analytical Methods in Chemistry, 2019: 1-7.
Hasanah, A.N., Soni, D., Pratiwi, R., Rahayu, D., Megantara, S., dan Mutakin, 2020, Synthesis of Diazepam-Imprinted Polymers with Two Functional Monomers in Chloroform Using a Bulk Polymerization Method, Journal of Chemistry, 2020: 1-8.
Fauziah, S., 2016, Sintesis, Karakterisasi dan Penggunaan Polimer Bercetakan Molekul untuk Ektraksi Fase Padat β-Sitosterol, Disertasi, Sekolah Pascasarjana Universitas Hasanuddin, Makassar.
Mayes, A.G., dan Whitcombe, M.J., 2005, Synthetic Strategies for the Generation of Molecularly Imprinted Organic Polymers, Advanced Drug Delivery Review, 57: 1742-1778.
Cacho, C., Turiel, E., Esteban, A. M., Conde, C. P., Cámara, C., 2004, Characterisation And Quality Assessment Of Binding Sites on a Propazine-Imprinted Polymer Prepared by Precipitation Polymerization, Journal of Chromatography B, 802: 347–353
Jing, T., Gao, X.D., Wang, P., Wang, Y., Lin, Y.F., Chen, X.Z., Zhou, Y.K., Mei, S.R.,2007, Preparation of High Selective Molecularly Imprinted Polymers for Tetracycline by Precipitation Polymerization, Chinese Chemical Letters, 18(2007): 1535-1538.
Tabarestani, M.S., Rahnama, K., Jahanshahi, M., Nasrollanejad, S., dan Fatemi, M.H., 2016, Synthesis of a Nanoporous Molecularly Imprinted Polymers for Dibutyl Phthalate Extracted from Trichoderma harzianum, J.Nanostruct, 6(3): 245-249.
Yang, Z., Chen, F., Tang, Y., dan Li, S., 2015, Selective Adsorption of Di(2-Ethylhexyl) Phthalate by Surface Imprinted Polymers with Modified Silica Gel as Functional Support, Journal of the Chemical Society of Pakistan, 37(5): 939- 949.
Yusof, N.A., Appribeyan, M.D., dan Harson, J., 2010, Synthesis and Characterization of a Molecularly Imprinted Polymer for Pb2+ Uptake using 2-vinyl pyridine as the Complexing Monomer, Sains Malaysiana, 39(5): 829-835.
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