THE EFFECT OF ADDITION BY BUTHYLATED HYDROXYTOLUENE (BHT) ON PHYSICAL PROPERTIES OF GEOMEMBRANE FROM RECYCLED HIGH DENSTY POLYETHYLENE (HFPE) PLASTIC WASTE

Authors

  • Veren Fransiska Department of Chemistry, Faculty of Science, Tanjungpura University
  • Intan Syahbanu Department of Chemistry, Faculty of Science, Tanjungpura University
  • Adhitiyawarman Adhitiyawarman Department of Chemistry, Faculty of Science, Tanjungpura University

DOI:

https://doi.org/10.26418/indonesian.v6i1.62725

Abstract

Recycled High Density Polyethylene (HDPE) has been prepared for geomembrane construction material. The aim of this research was to study the effect of Butylated Hydroxytoluene (BHT) addition as an antioxidant on the characteristics of the resulting geomembrane. Fourier Transform Infra Red (FTIR) analysis was carried out to examine functional groups of recycled HDPE and prepared geomembranes. Mechanical properties, permeability and hydrophobicity of geomembrane were observed to determined optimum BHT addition. The results of FTIR analysis on recycled HDPE showed the presence of functional groups at wavelengths 2912 and 2847 cm-1 (C-H stretching); 1474 and 1467 cm-1 (CH2 bend); 721 cm-1 (CH2 Rock). After being formulated with other materials to obtain geomembranes, it was not found new peak indicating that the presence of BHT in geomembrane only physical interaction occurs. All of geomembranes had no permeability to water and reach 100% of hydrophobicity. The highest ­ tensile test value was shown by geomembrane with 0,25 b/b% of BHT which about 21.235 MPa and 16.01 MPa for before and after soil burial test for four weeks, respectively. Perhaps might be due to the interaction between BHT at low concentrations which has lower polarity and HDPE which is nonpolar has better compatibility than at other concentrations

References

World Bank Group. (2018). Hotspot Sampah Laut Indonesia. Public Discl. Auth

Azzamataufiq, B., and Aditya, W.P. (2016). Pengaruh Campuran Bahan Bakar Premium Dengan Plastik Polypropilene ( PP ) Hasil Piropilis Terhadap Nilai Kalor Bahan Bakar. in Seminar Hasil Penelitian dan Pengabdian Masyarakat Dana BOPTN Tahun 2016 (pp. 5–10).

Lavoie, F.L., Kobelnik, M., Valentin, C. A., Lins da Silva, J., and de L, Lopes, M. (2020). Study of an exhumed HDPE geomembrane used in an industrial water pond: Physical and thermoanalytical characterisations. Results Mater, 8:1–20. doi: 10.1016/j.rinma.2020.100131.

Koerner, R.M., Hsuan, Y.G., and Koerner, G.R. (2011). Geomembrane Lifetime Prediction: Unexposed and Exposed Conditions. GRI White Paper #6. Folsom, USA.

Effendi, R. (2011). Geomembrane-Geotextile Interface Friction. J. Teknol. Berkelanjutan, 1(1):1–9.

Shirazi, S. G., Valipourian, K., and Golhashem, M. R. (2019). A Review on Geomembrane Characteristics and Application in Geotechnical Engineering. World Acad. Sci. Eng. Technol. Int. J. Civ. Environ. Eng, 13(8):494–501.

Palmeira, E. M., Araújo, G. L. S., and Santos, E. C. G. (2021). Sustainable solutions with geosynthetics and alternative construction materials—a review. Sustain, 13(22):1–29. doi: 10.3390/su132212756.

Mafra, J. M. Q., Mello, J., Eldridge, T., and Breul, B. (2008). Two Case Histories of Dams Waterproofing with Bituminous Geomembrane. In The First Pan American Geosynthetics Conference & Exhibition (pp. 1626–1635).

Lavoie, F.L., Kobelnik, M., Valentin, C. A., Lins da Silva, J., and de L, Lopes, M. (2020). HDPE geomembranes for environmental protection: Two case studies. Sustain, 12(20):1–19. doi: 10.3390/su12208682.

Rowe, R. K., Islam, M. Z., Brachman R. W. I., Arnepalli, D. N., and Ewais, A. R. (2010). Antioxidant Depletion from a High Density Polyethylene Geomembrane under Simulated Landfill Conditions. J. Geotech. Geoenvironmental Eng, 136(7):930–939. doi: 10.1061/(asce)gt.1943-5606.0000302.

Hope, N and Bellare, A. A. (2015). Comparison of the Efficacy of Various Antioxidants on the Oxidative Stability of Irradiated Polyethylene. Clinical Orthopaedics and Related Research, 473(3):936–41.

Fasihnia, S. H., Peighambardoust, S. H., Peighambardoust, S. J., Oromiehie, A., Soltanzadeh, M., and Peressini, D. (2020). Migration analysis, antioxidant, and mechanical characterization of polypropylene-based active food packaging films loaded with BHA, BHT, and TBHQ. J. Food Sci, 85(8):2317–2328. doi: 10.1111/1750-3841.15337.

Amran, N. H., and Ghani, A. N, A. (2015). Falling head test for geotextile drainage capacity. J. Teknol, 75(5):89–93. doi: 10.11113/jt.v75.5075.

Al-Shaeli, M., Smith, S. J. D., Jiang, S., Wang, H., Zhang, K., and Ladewig, B. P. (2021). Long-term stable metal organic framework (MOF) based mixed matrix membranes for ultrafiltration. J. Memb. Sci, 635:119339. doi: 10.1016/j.memsci.2021.119339.

Alam, M., and Amalia, R. (2020). Pengaruh Filler Bentonit Terhadap Sifat Hidrofobisitas Pada Bioplastik Berbasis Pati Ampas Sagu. Indonesia Journal of Chemical Technology, 1(1):2715–8764.

Purnami., Wardana, I., and K, V. (2015). Pengaruh Penggunaan Katalis Terhadap Laju dan Efisiensi Pembentukan Hidrogen. J. Rekayasa Mesin, 6(1):51–59.

Achilias, D. S., Antonakous, E., Roupakias, C., Megalokonomos, P., and Lappas, A. (2008). Recycling techniques of polyolefins from plastic wastes. Glob. Nest J, 10(1):114–122. doi: 10.30955/gnj.000468.

Jung, M. R., Horgen, F. D., Orski, S. V., C, V. R., La Beers, K., Balazs, G. H., Jones, T. T., Work, T. M., Brignac, K. C., Royer, S. J., Hyrenbach, K. D., Jensen, B. A., and Lynch, J.M. (2018). Validation of ATR FT-IR to identify polymers of plastic marine debris, including those ingested by marine organisms. Mar. Pollut. Bull, 127:704–716. doi: 10.1016/j.marpolbul.2017.12.061.

Rowe, R. K., Abdelaal, F. B., Zafari, M., Morsy, M. S., Priyanto, and D. G. (2020). An approach to high-density polyethylene (Hdpe) geomembrane selection for challenging design requirements. Can. Geotech. J, 57(10):1550–1565. doi: 10.1139/cgj-2019-0572.

Departemen Permukiman Dan Prasarana Wilayah. (2004). Penanganan tanah ekspansif dengan geomembran sebagai penghalang kelembaban vertikal. In PEDOMAN Konstruksi dan Bangunan Pd T-11-2004-B (pp. 1–17).

Shirsath, M., and Choudhari, K. (2018). Role of Geosynthetics in sustainable development. Int. J. Acad. Res. Dev, 3(2):89–93.

Sugatri, R.I., Wirasadewa, Y.C., Saputro, K.E., Muslih, E.Y., Ikono, R., and Nasir, M. (2018). Recycled carbon black from waste of tire industry: thermal study. Microsystem Technology, 24(1):749–55. doi: 10.1007/s00542-017-3397-6

Sahu, A. K., Sudhakar, K., and Sarviya, R. M. (2020). U.V light effect on the mechanical behaviour of HDPE/Carbon black composites. In IOP Conference Series: Materials Science and Engineering 788(1). doi: 10.1088/1757-899X/788/1/012054.

Koerner, R. M., and Hsuan, Y. G. (2003). Lifetime Prediction of Polymeric Geomembranes Used in New Dam Construction and Dam Rehabilitation. In Proceedings Assoc. of State Dam Safety Officials Conference (pp.16).

Ng, H. (2009). HDPE Lined Water Reservoirs For Power Generating Stations. In Proceeding of the 4th Asian Regional Conference and Geosynthetics. (pp.1–7). doi: 10.1007/978-3-540-69313-0.

Kocak, Y. (2019). Scholar Commons Thermo-Oxidative Degradation of HDPE Geomembranes : Effect of Phenolic Antioxidant and Hindered Amine Light Stabilizer Concentrations. (Master Thesis), University of South Florida.

Kelechi, U. P., Okeke, O. C., and State, I. (2018). Geotextiles and Geomembranes : Properties , Production and Engineering Applications. Int. J. Adv. Acad. Res, 4(11):17–32.

Rowe, R. K., Rimal, S., Arnepalli, D. N., and Bathurst, R. J. (2009). Durability of fluorinated high density polyethylene geomembrane in the Arctic. Geotext. Geomembranes, 28(1):100–107. doi: 10.1016/j.geotexmem.2009.10.012.

Wijayanto, A., Juwono, P., and Cahya, E. (2021). The Influence of Damage to the Geomembrane Layer on the Seepage Pattern and Discharge at the Homogeneous Embankment Dam. Civ. Environ. Sci, 4(1):076–083. doi: 10.21776/ub.civense.2021.00401.7.

Shukla, S., Kumar and Yin, J.-H. (2006). Fundamentals of Geosynthetic Engineering. Taylor and Francis: UK, London.

Rowe, R. K., Sangam, H. P., and Lake, C. B. (2003). Evaluation of an HDPE geomembrane after 14 years as a leachate lagoon liner. Can. Geotech. J, 40,(3):536–550. doi: 10.1139/t03-019.

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2023-04-30

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