SINTESIS, KARAKTERISASI, DAN APLIKASI POLIANILIN SEBAGAI POLIMER KONDUKTIF DALAM TEKNOLOGI MODERN: A REVIEW

Authors

  • Fitra Ahmad Rifa'i Universitas Negeri Semarang
  • Dewa Kahfi Saputra Universitas Negeri Semarang
  • Mahatma Apriliana Universitas Negeri Semarang
  • Luthfa Abibah Nur Abidin Universitas Negeri Semarang
  • Harjono Harjono Universitas Negeri Semarang

DOI:

https://doi.org/10.26418/indonesian.v8i2.94479

Abstract

Polyaniline (PANI) is a widely studied conductive polymer known for its high electrical conductivity, environmental stability, and ease of synthesis. This review critically summarizes the chemical and electrochemical synthesis routes of PANI, along with its structural and electronic characterization using FTIR, UV"“Vis Spectroscopy, X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM), electrical conductivity analysis, and X-ray Photoelectron Spectroscopy (XPS). Furthermore, it highlights the recent advancements in PANI applications across modern technologies, including chemical sensors, biosensors, supercapacitors, lithium-ion batteries, and biomedical devices. By analyzing 68 peer-reviewed articles published within the last decade, this work emphasizes the impact of synthesis parameters and structural modifications on the functional performance of PANI. While PANI offers promising potential, challenges like poor solubility and mechanical limitations remain. This review aims to bridge synthesis, structure, and application relationships and propose future directions for enhancing PANI"™s multifunctionality through nanocomposites and dopant engineering.

Author Biographies

Fitra Ahmad Rifa'i, Universitas Negeri Semarang

Department of Chemistry, Universitas Negeri Semarang. Undergraduate student.

Dewa Kahfi Saputra, Universitas Negeri Semarang

Department of Chemistry, Universitas Negeri Semarang. Undergraduate student.

Mahatma Apriliana, Universitas Negeri Semarang

Department of Chemistry, Universitas Negeri Semarang. Undergraduate student.

Luthfa Abibah Nur Abidin, Universitas Negeri Semarang

Department of Chemistry, Universitas Negeri Semarang. Undergraduate student.

Harjono Harjono, Universitas Negeri Semarang

Department of Chemistry, Universitas Negeri Semarang. Lecturer.

References

Daftar Pustaka

Poddar, A.K., Patel, S.S., & Patel, H.D. (2021). Synthesis, characterization and applications of conductive polymers: A brief review. Polymer Advanced Technologies, 32(12):4616-4641. https://doi.org/10.1002/pat.5483.

Bhandari, S. (2018). Polyaniline: Structure and Properties Relationship. In Polyaniline Blends, Composites, and Nanocomposites, Chapter 2, pp. 23–49. Amsterdam: Elsevier. https://doi.org/10.1016/B978-0-12-809551-5.00002-3.

Beygisangchin, M., Abdul Rashid, S., Shafie, S., Sadrolhosseini, A.R., & Lim, H.N. (2021). Preparations, properties, and applications of polyaniline and polyaniline thin films—a review. Polymers, 13(12):2003. https://doi.org/10.3390/polym13122003.

Andari, D., Yudha S, S., & Adfa, M. (2022). Komposit polianilin/logam oksida: sintesis, karakterisasi dan aplikasi: sebuah telaah pustaka. Rafflesia Journal of Natural and Applied Sciences, 2(1):128-134. https://doi.org/10.33369/rjna.v2i1.24443.

Syafei, D.I., Rini, E.P., Paristiowati, M., Imaduddin, A., & Budi, S. (2022). Synthesis and Characterization of High Conductivity Polyaniline Prepared at Room Temperature. In Chem. Mater. 1(1):7-11. https://doi.org/10.56425/cma.v1i1.21.

Das, P., Deoghare, A.B., & Ranjan Maity, S. (2023). Fabrication and characterization of polyaniline (PANI) modified with reduced graphene oxide (RGO) nanosheets. Materials Today: Proceedings, 72:2306–2314. https://doi.org/10.1016/j.matpr.2022.09.397.

Mustafa, Z,. Ghadai, R.K., Pradhan, B.B., Swain, B.P., Biswas, J., & Kumar, D. (2024). Recent advances in polyaniline/graphene nanocomposites for supercapacitor applications: Synthesis, properties, and future directions. Results in Surfaces and Interfaces, 17:100316. https://doi.org/10.1016/j.rsurfi.2024.100316.

Aras, N.R.M., & Irwan, M. (2024). Sintesis polianilin (PANi) dengan metode polimerisasi interfasial sebagai bahan dasar pembuatan sensor gas amonia (NH3). Jurnal Teknik Mesin Indonesia, 19(1):33–41. https://doi.org/10.36289/jtmi.v19i1.561.

Zarrintaj, P., Vahabi, H., Saeb, M.R., & Mozafari, M. (2019). Application of polyaniline and its derivatives. In Fundamentals and Emerging Applications of Polyaniline, Chapter 14, pp. 259-272. Amsterdam: Elsevier. https://doi.org/10.1016/B978-0-12-817915-4.00014-2.

Babel, V., & Hiran, B.L. (2021). A review on polyaniline composites: Synthesis, characterization, and applications. Polymer Composites, 42(7):3142-3157. https://doi.org/10.1002/pc.26048.

Prasutiyo, Y.J., Manaf, A., & Hafizah, M.A.E. (2020). Synthesis of polyaniline by chemical oxidative polymerization and characteristic of conductivity and reflection for various strong acid dopants. Journal of Physics: Conference Series, 1442(1), 1-6. https://doi.org/10.1088/1742-6596/1442/1/012003.

Dayawati, Saifan, A.A.A., Singh, V.H., Upadhye, G.C., Sharma, S., & Bhattacharya, S. (2023). Synthesis, Properties, Nanocomposites, and Electrochemical Applications of Polyaniline: A Review. Journal of Polymer and Composites, 11(3):13–20. https://doi.org/10.37591/JoPC.

Mir, A., Kumar, A., & Riaz, U. (2022). A short review on the synthesis and advance applications of polyaniline hydrogels. RSC Advances, 12:19122–19132. https://doi.org/10.1039/D2RA02674K.

Banjar, M.F., Abedin, F.N.J., Fizal, A.N.S., Sarih, N.M, Hossain, S., Osman, H., Khalil, N.A., Yahaya, A.N.A, & Zulkifli, M. (2023). Synthesis and Characterization of a Novel Nanosized Polyaniline. Polymers, 15(23):4565. https://doi.org/10.3390/polym15234565.

Saeb, M.R., Zarrintaj, P., Khandelwal, P., & Chauhan, N.P.S. (2019). Synthetic route of polyaniline (I): Conventional oxidative polymerization. Fundamentals and Emerging Applications of Polyaniline, Chapter 2, pp. 17-41. Amsterdam: Elsevier. https://doi.org/10.1016/B978-0-12-817915-4.00002-6.

Zhao, Y., Wei, H., Arowo, M., Yan, X., Wu, W., Chen, J., Wang, Y., & Guo, Z. (2014). Electrochemical energy storage by polyaniline nanofibers: high gravity assisted oxidative polymerization vs. rapid mixing chemical oxidative polymerization. Physical Chemistry Chemical Physics, 17(2), 1498–1502. https://doi.org/10.1039/c4cp03144j.

Saeb, M. R., Zarrintaj, P., Khandelwal, P., & Chauhan, N. P. S. (2019). Synthetic route of polyaniline (I): Conventional oxidative polymerization. In Elsevier eBooks (pp. 17–41). https://doi.org/10.1016/b978-0-12-817915-4.00002-6.

Deb, K., Bera, A., & Saha, B. (2016). Tuning of electrical and optical properties of polyaniline incorporated functional paper for flexible circuits through oxidative chemical polymerization. RSC Advances, 6(97), 94795–94802. https://doi.org/10.1039/c6ra16079d.

Smolin, Y. Y., Soroush, M., & Lau, K. K. S. (2017). Oxidative chemical vapor deposition of polyaniline thin films. Beilstein Journal of Nanotechnology, 8, 1266–1276. https://doi.org/10.3762/bjnano.8.128.

Nigmatullin, R.R., Budnikov, H.C., Mustafin, A.G., Sidelnikov, A.V., Andrilanova, A.N., & Shigapova, A.R. (2019). Process of electrochemical electrode modification by polyaniline in the frame of percolation model. J Solid State Electrochem, 23:1221–1235. https://doi.org/10.1007/s10008-019-04217-5.

Wang, P., Wang, T., Lin, W., Lin, H., Lee, M., & Yang, C. (2018). Enhanced Supercapacitor Performance Using Electropolymerization of Self-Doped Polyaniline on Carbon Film. Nanomaterials, 8(4):214. https://doi.org/10.3390/nano8040214.

Ferrag, C., Noroozifar, M., Alam, A.R.M., & Kerman, K. (2022). Graphene oxide hydrogel electrolyte for improving the performance of electropolymerized polyaniline solar cells. Journal of Power Sources, 542:231796. https://doi.org/10.1016/j.jpowsour.2022.231796.

Abalyaeva, V. V., & Efimov, O. N. (2015). The Effect of Electroactive Anions on Synthesis and Electrochemical Behavior of Polyanyline. Application Perspectives. Alternative Energy and Ecology (ISJAEE), 12, 40–57. https://doi.org/10.15518/isjaee.2015.12.004

Das, G., & Yoon, H.H. (2015). Amperometric urea biosensors based on sulfonated graphene/polyaniline nanocomposite. International Journal of Nanomedicine, 10(1):55-66. https://doi.org/10.2147/IJN.S88315.

Yan, S., Guo, Z., Ge, Z., Zhang, B., Zhang, Y., Li, Y., Wang, M., & Ge, X. (2025). Study on the Radiation Synthesis Mechanism and the Electrochemical Property of Polyaniline. Chinese Journal of Polymer Science, 43:328-340. https://doi.org/10.1007/s10118-025-3258-1.

Popovic, N., Jugovic, B., Jokic, B., Jugovc, Z.K., Stevanovic, J., Grgur, B., & Gvozdenovic, M. (2015). Electrochemical template-free synthesis of nanofibrous polyaniline and its application for ascorbic acid determination. International Journal of Electrochemical Science, 10(2):1208–1220. https://doi.org/10.1016/S1452-3981(23)05066-6.

Mrad, M., Amor, Y.B., Dhouibi, L., & Montemor, F. (2017). Electrochemical study of polyaniline coating electropolymerized onto AA2024-T3 aluminium alloy: Physical properties and anticorrosion performance. Synthetic Metals, 234:145–153. https://doi.org/10.1016/j.synthmet.2017.11.002.

Nautiyal, A., Cook J.E., & Zhang, X. (2019). Tunable electrochemical performance of polyaniline coating via facile ion exchanges. Progress in Organic Coatings, 136:105309. https://doi.org/10.1016/j.porgcoat.2019.105309.

Tomšík, E., Dallas, P., Sedenkova, I., Svoboda J., & Hruby, M. (2021). Electrochemical deposition of highly hydrophobic perfluorinated polyaniline film for biosensor applications. RSC Advances, 11:18852–18859. https://doi.org/10.1039/d1ra02325j.

Cui, G., Wang, R., Guan, Y., Li, J., Li, Y., Zhao, Y., & Wang, H. (2024). In-situ electropolymerized polyaniline nanoparticles grown on longan shell-derived porous carbon for high-performance supercapacitor electrode. Journal of Electroanalytical Chemistry, 963:118293. https://doi.org/10.1016/j.jelechem.2024.118293.

Messabhia, A., Boudellioua, H., hamlaoui, Y., & Pedraza, F. (2025). Electrochemical deposition of graphene-doped polyaniline films for enhanced zinc corrosion resistance. Applied Surface Science, 701:163311. https://doi.org/10.1016/j.apsusc.2025.163311.

Jose, A., Bansal, M., Svirskis, D., Swift, S., & Gizdavic-Nikolaidis, M.R. (2024). Synthesis and characterization of antimicrobial colloidal polyanilines. Colloids and Surfaces B: Biointerfaces, 238:113912. https://doi.org/10.1016/j.colsurfb.2024.113912.

Silva, D.C.T, Silva, M.L.M., Farias, P.H.M., Galvão, C.C., Costa, E.M.S., Melo, R.A., Medeiros, E.B.M., & Filho, N.M.L (2025). Synthesis and characterization of polyaniline, sucrose octaacetate and chitosan blend for removal of remazol black by adsorption: Equilibrium, kinetics, and regeneration. International Journal of Biological Macromolecules, 289:138863. https://doi.org/10.1016/j.ijbiomac.2024.138863.

Raj, P., Oh, M., Han, K., & Lee, T. (2021). Label-free electrochemical biosensor based on Au@MOS2–PANI for Escherichia coli detection. Chemosensors, 9(3):49. https://doi.org/10.3390/chemosensors9030049.

Modak, P., Kondawar, S. B., & Nandanwar, D. (2015). Synthesis and characterization of conducting Polyaniline/Graphene nanocomposites for electromagnetic interference shielding. Procedia Materials Science, 10, 588–594. https://doi.org/10.1016/j.mspro.2015.06.010

Devi, M.R., Saranya, A., Pandiarajan, J., Dharmaraja, J., Prithivikumaran, N., & Jeyakumaran, N. (2019). Fabrication, spectral characterization, XRD and SEM studies on some organic acids doped polyaniline thin films on glass substrate. Journal of King Saud University – Science, 31(4):1290-1296. https://doi.org/10.1016/j.jksus.2018.02.008.

Narasimhachar, R., Basavaraj, B., Vijaykumar, B.T., & Sannakki, B. (2023). Studies on the electrical properties of polyaniline with cadmium oxide nanocomposites. Materials Today : Proceedings, 92(2):1676-1680. https://doi.org/10.1016/j.matpr.2023.06.304.

Li, L., Du, D., Hem C., Han, K., Xu, W., Xia, L., Cai, G., Cui, X., Chen, Y., Yu, L., & Kong, L. (2024). Electrodeposition of polyaniline on reduced graphene oxide/cotton yarn with tunable electrochemical performance for flexible textile supercapacitors. Polymers, 306:127200. https://doi.org/10.1016/j.polymer.2024.127200.

Dinpanah, E., Lakouraj, M.M., Fooladi, E., & Hasantabar, V. (2024). Synthesis and characterization of a nanostructure conductive copolymer based on polyaniline and polylactic acid as an effective substrate in proteins impedimetric biosensing. RSC Advances, 14(18):12600-12611. https://doi.org/10.1039/d4ra01061b.

Jamil, S., Ahmad, Z., Ali, M., Khan, S.R., Ali, S., Hammami, M.A., Haroon, M., & Saleh, T.A. (2021). Synthesis and characterization of polyaniline/nickel oxide composites for fuel additive and dyes reduction. Chemical Physics Letters, 776:138713. https://doi.org/10.1016/j.cplett.2021.138713.

Zuo, Y., Kang, X., Du, B., & Zuo, Z. (2023). Fabrication and characterization of conductive polyaniline-decorated Na3V2(PO4)3 cathode for Na-ion batteries. Solid State Ionics, 400:116338. https://doi.org/10.1016/j.ssi.2023.116338.

Stejskal, J., Trchová, M., KuÄka, J., Capáková, Z., HumpolíÄek, P., & ProkeÅ¡, J. (2021). Effect of sterilization techniques on the conductivity of polyaniline and polypyrrole. Synthetic Metals, 282:116937. https://doi.org/10.1016/j.synthmet.2021.116937.

Kedang, Yohana I. (2018). Review: Characterization and Modification of Polyamide Membrane for Color Substance Separation Applications. Jurnal Saintek Lahan Kering, 1(2): 28-30, doi: https://doi.org/10.32938/slk.v1i2.568.

Lyutov, V., Kabanova, V., Gribkova, O., Nekrasov, A., & Tsakova, V. (2020). Electrochemically-obtained polysulfonic-acids doped polyaniline films—A comparative study by electrochemical, microgravimetric and XPS methods. Polymers, 12(5), 1050. https://doi.org/10.3390/polym12051050.

Mahat, M. M., Mawad, D., Nelson, G. W., Fearn, S., Palgrave, R. G., Payne, D. J., & Stevens, M. M. (2015). Elucidating the deprotonation of polyaniline films by X-ray photoelectron spectroscopy. Journal of Materials Chemistry C, 3(27), 7180–7186. https://doi.org/10.1039/C5TC01038A.

Quílez-Bermejo, J., Morallón, E., & Cazorla-Amorós, D. (2020). Polyaniline-Derived N-Doped Ordered Mesoporous Carbon Thin Films: Efficient Catalysts towards Oxygen Reduction Reaction. Polymers, 12(10), 2382. https://doi.org/10.3390/polym12102382.

Wang, Z., Zhu, M., Pel, Z., Xue, Q., Li, H., Huang, Y., & Zhi C. (2020). Polymers for supercapacitors: Boosting the development of the flexible and wearable energy storage. Materials Science & Engineering: R: Reports, 139:100520. https://doi.org/10.1016/j.mser.2019.100520.

Eftekhari, A., Li, L., & Yang, Y. (2017). Polyaniline supercapacitors. Journal of Power Sources, 347:86–107. https://doi.org/10.1016/j.jpowsour.2017.02.054.

Puttaningaiah, K.P.C.H (2025). Design and optimization of polyaniline/swcnt anodes for improved lithium-ion storage. Polymers, 17(4):478. https://doi.org/10.3390/polym17040478.

Ali, F., Noor, S., Ahmad, F., Nazir, S., & Nasar, G. (2023). PANI-based nanocomposites for electrical applications: a review. Journal of Materials and Physical Sciences, 4(1):46-60. https://doi.org/10.52131/jmps.2023.0401.0035.

Li, Z., & Gong, L. (2020). Research progress on applications of polyaniline (pani) for electrochemical energy storage and conversion. Materials, 13(3):548. https://doi.org/10.3390/ma13030548.

Boota, M., & Gogotsi, Y. (2018). Mxene—conducting polymer asymmetric pseudocapacitors. Advanced Energy Materials, 9(7):1802917. https://doi.org/10.1002/aenm.201802917.

Choudhari, U., & Jagtap, S. (2023). A panoramic view of NO and NH3 gas sensors. Nano-Structures & Nano-Objects, 35:100995. https://doi.org/10.1016/j.nanoso.2023.100995.

Fang, F., Dong, Y., & Choi, H. (2018). Effect of oxidants on morphology of interfacial polymerized polyaniline nanofibers and their electrorheological response. Polymer, 158:176-182. https://doi.org/10.1016/j.polymer.2018.10.065.

Lai, J., Yi, Y., Shen, J., Wu, K., Zhang, L., & Liu, J. (2016). Polyaniline-based glucose biosensor: A review. Journal of Electroanalytical Chemistry, 782:138-153. https://doi.org/10.1016/j.jelechem.2016.10.033.

German, N., RamanaviÄienÄ—, A., & RamanaviÄius, A. (2021). Dispersed conducting polymer nanocomposites with glucose oxidase and gold nanoparticles for the design of enzymatic glucose biosensors. Polymers, 13(13):2173. https://doi.org/10.3390/polym13132173.

Tirgil, N.Y., Kalkan, Z., Öztürk, S., Sürdem, S., & Öktem, M.F. (2022). Electrochemical enzymatic biosensor development by using different electropolymerization conditions of polyaniline. Düzce Üniversitesi Bilim Ve Teknoloji Dergisi, 10(2):929-939. https://doi.org/10.29130/dubited.844331.

Kazemi, F., Naghib, S.M., Zare, Y., & Rhee, K.Y. (2021). Biosensing Applications of Polyaniline (PANI)-Based Nanocomposites: A Review. Polymer Reviews, 61(3):553–597. https://doi.org/10.1080/15583724.2020.1858871.

Kaushik, P., Bharti, R., Sharma, R., Verma, M., Olsson, R. T., & Pandey, A. (2024). Progress in synthesis and applications of Polyaniline-Coated Nanocomposites: A comprehensive review. European Polymer Journal, 221:113574. https://doi.org/10.1016/j.eurpolymj.2024.113574.

Zhang, Y., Zhou, M., Dou, C., Ma, G., Wang, Y., Feng, N., Wang, W., & Fang, L. (2018). Synthesis and biocompatibility assessment of polyaniline nanomaterials. Journal of Bioactive and Compatible Polymers, 34(1), 16-24. https://doi.org/10.1177/0883911518809110.

Zarrintaj, P., Ahmadi, Z., Vahabi, H., Ducos, F., Saeb, M.R., & Mozafari, M. (2018). Polyaniline in retrospect and prospect. Materials Today: Proceedings, 5(7):15852–15860. https://doi.org/10.1016/j.matpr.2018.05.084.

Chauhan, N.P.S., & Mozafari, M. (2019). Polyaniline: Future perspectives. In Fundamentals and Emerging Applications of Polyaniline, Chapter 15, pp. 273–280. Amsterdam: Elsevier. https://doi.org/10.1016/B978-0-12-817915-4.00015-4.

Ahsan, Q. A., Kusumawati, D. H., & Fitriana. (2024). Karakteristik Komposit PANI/GO sebagai Elektroda Superkapasitor. Jurnal Inovasi Fisika Indonesia, 13(3), 74-81. https://doi.org/10.26740/ifi.v13n3.p74-81.

Manaf, A., Prasutiyo, Y. J., Hafizah, M. E., & Andreas. (2017). Conductivity Enhancement of Polyaniline Through Chemical Oxidative Polymerization Assisted by Strong Acid Dopants. International Journal of Mechanical and Production Engineering, 5(2), 127-131.

Ariyanti, P. R., & Putri, N. P. (2023). Karakteristik Lapisan Tipis Polianilin sebagai Bahan Aktif Sensor Gas Benzene. Jurnal Inovasi Fisika Indonesia, 13(1), 21-26. https://doi.org/10.26740/ifi.v13n1.p21-26.

Roida, E. D., & Putri, N. P. (2020). Aplikasi Polianilin Sebagai Bahan Aktif Pendeteksi Alkohol. Jurnal Inovasi Fisika Indonesia, 9(2), 152-162. https://doi.org/10.26740/ifi.v9n2.p152-162.

Kaushik, P., Bharti, R., Sharma, R., & Pandey, A. (2025). Synthesis of polyaniline-encapsulated silver nanocomposites to improve removal efficacy of anti-alzheimer drug from aqueous solution and evaluation of their antioxidant properties. Environmental Science: Advances, 4, 1250-1266. https://doi.org/10.1039/d5va00107b.

Agilan, P., & Rajendran, N. (2018). In-vitro bioactivity and electrochemical behavior of polyaniline encapsulated titania nanotube arrays for biomedical applications. Applied Surface Science, 439, 66-74. https://doi.org/10.1016/j.apsusc.2017.12.258.

Downloads

Published

2025-08-29

Issue

Section

Articles