Pengaturan Tingkat Oksidasi Polimer Konduktif PANi-HCl Melalui Pendopingan
DOI:
https://doi.org/10.26418/positron.v1i1.1568Keywords:
Polimer Konduktif, Polianilin, Polimerisasi, Pendopingan, Tingkat OksidasAbstract
Penelitian ini mengkaji tentang tingkat oksidasi berdasarkan data spektrofotometri FT-IR polimer konduktif polianilin, PANi yang didoping oleh HCl hasil elektropolimerisasi galvanostatis. Polimerisasi dilakukan pada arus konstan 3 mA dengan variasi konsentrasi dopan 1M, 1,5 M, 2 M, 2,5 M dan 3 M. Hasil penentuan dan analisis terhadap tingkat-tingkat oksidasi PANi yang terdoping menunjukkan bahwa tingkat oksidasi PANi berubah terhadap konsentrasi dopan HCl dan berdasarkan tingkat oksidasi tersebut dapat diduga bahwa PANi yang menghasilkan konduktivitas listrik tertinggi adalah yang didoping oleh HCl 1 M dengan tingkat oksidasi 0,5.
References
Ibrahim, Medhat and Eckhard Koglin. Spectroscopic Study of Polyaniline Emeraldine Base: Modelling Approach. Acta Chim. Slov. 52(2005) 159–163
Kang, E.T., K.G. Neoh and K.L. Tan., 1998. Polyaniline: Polymer with Many Interseting Intrinsic Redox State. Prog. Polym. Sci. Vol. 23, 277-324(1998)
MacDiarmid, Alan G. 2002. Synthetic Metals:a Novel Role for Organic Polymers. Synthetic Metals 125(2002) 11-12
McGovern,Scott T., Geoffrey M. Spinks and Gordon G. Wallace. 2005. Micro-humidity sensors based on a processable polyaniline blend. Sensors and Actuators B 107 (2005) 657–665
Malino, Mariana., 2010.
Mark J.E., 2007.Physical Properties of Polymers Handbook, 2nd ed., Springer Science Business Media, LLC. New York
Mickova,Irena, Abdurauf Prusi, Toma Gr_ev and Ljubomir Arsov. 2006. Electrochemical Polymerization of Aniline in Presence of Partikel-nano TiO2. Bulletin of the Chemists and Technologists of Macedonia, Vol. 25, No. 1, pp. 45–50 (2006)
Sadek et al, 2007, A Layered Surface Acoustic Wave Gas Sensor Based on a Polyaniline/In2O3 Nanofibre Composite , Paper 2425, University of California
Sajeev, C. U.S., Joseph Mathai, S. Saravanan, Rajeev R. Ashokan, S. Venkatachalam and M. R. Anantharaman. On the Optical and Electrical Properties of RF and A.C. Plasma Polymerized Aniline Thin Films. Bull. Mater. Sci., Vol. 29, No. 2(2006) pp. 159–163
Teoh, Geik Ling, Kong Yong Liew and Wan A.K. Mahmood. Preparation of polyaniline-Al2O3 Composites Nanofibers with Controllable Conductivity. Materials Letters 61 (2007) 4947–4949
Urbanczyk, Marian, Wiesław Jakubik, Erwin Maciak and Agnieszka Stolarczyk. 2004. Investigations of Polyaniline Thin Films as a Toxic Gas Sensors in Saw and Electric System-Preeliminary. Molecular and Quantum Acoustics vol. 25, (2004)
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