SINTESIS TiO2 TERDOPING Bi3+ DAN UJI AKTIVITAS FOTOKATALISIS ANTIBAKTERI E.coli DENGAN BANTUAN SINAR TAMPAK (SYNTHESIS OF Bi3+ DOPED TiO2 AND PHOTOCATALYSIS ACTIVITY TEST OF E.coli ANTIBACTERIA UNDER VISIBLE IRRADIATION)
DOI:
https://doi.org/10.26418/indonesian.v4i2.46976Abstract
The synthesis of Bi3+ doped TiO2 was carried out using the sol-gel method with the precursor solution of titanium tetraisopropoxide (TTiP). Bi3+ cation dopant is done to reduce the energy of the TiO2 band gap so that it can be active in the visible light region. The synthesized Bi(III) "“TiO2 photocatalyst was characterized using DRS UV-Vis, FTIR, and EDX. The results of the DRS UV-Vis analysis showed that 1% Bi(III) "“TiO2 photocatalyst had a bandgap energy of 2.79 eV or equivalent to a wavelength of 469.97 nm. Infrared spectra show that there is a unique absorption at the wave number 956,56 cm-1 which is the absorption of the vibration Bi-O-Ti group. Photocatalyst Bi(III) -TiO2 was then tested for antibacterial activity against E. coli in polluted water. The activity test was carried out using the turbidimetric method by UV-vis spectrophotometry. The results of the activity test for 120 minutes with the help of visible light showed that the photocatalyst Bi(III) "“TiO21% had the best antibacterial activity. The decrease in the number of E. coli in the water reached 48.54%.References
Sucahya, T.N., Permatasari, N., dan Nandiyanto, A.B.D. (2016). Review: Fotokatalis untuk Pengolahan Limbah Cair.Jurnal Integrasi Proses. 6(1):1-15.
Kumar, S.G., and Devi, L.G. (2011). Review and Modified TiO2 Photocatalysis under UV/Visible Light: Selected Results and Related Mechanisms on Interfacial Charge Carrier Transfer Dinamics.The Journal of Physical Chemistry. 115:13211-13241.
Sofyan, D.K. (2018). Peramalan Kebutuhan Klorin (Cl2) pada Bagian Produksi di PT Pupuk Iskandar Muda. Industrial Engineering Journal. 7(1):30-35.
Rame, Agus, P., dan Budiarto A. (2017). Pengolahan Air Limbah Tekstil Berbasis Ozoznisasi Katalitik dengan Katalis (Fe2O3) dan Aluminium Oksida (Al2O3) Menggunakan Difuser Mikro.Jurnal Riset Teknologi Pencegahan Pencemaran Industri. 8(2): 67-75.
Istingani, Noor, E., dan Suprihatin. (2017). Peningkatan Kualitas Pengolahan Air Bersih dengan Perbaikan Proses Oksidasi. Journal of Environmental Engineering and Waste Management. 2(2): 91-100.
Naimah, S., dan Ermawati, R. (2011). Efek Fotokatalis Nano TiO2 Terhadap Mekanisme Antimikroba E.coli dan Salmonella.Jurnal Riset Industri. 5(2).
Aritonang, A.B., Pratiwi, E., Warsidah, W., Nurdiansyah, S.I., Risko, R.. (2021). Fe-doped TiO2/Kaolinite as an Antibacterial Photocatalyst under Visible Light Irradiation. Bulletin of Chemical Reaction Engineering & Catalysis. 16 (2); 293-301.
Reddy, P.A.K., Srinivas, B., Kala, P., Kumari, V.D., and Subrahmanyam, M. (2011) Preparation and Characterization of Bi-Doped TiO2 and its Solar Photocatalytic Actuvity for the Degradation of Isoproturon Herbicide.Materials Research Bulletin. 46:1766-1771.
Mao, H., Jin, Z., Zhang, F., He, H., Chen, J., and Qian, Y.(2018). A High Efficiency Photocatalyst Based on Porous Bi-Doped TiO2 Composites.Ceramis International. 44:17535-17538.
Eddy, D.R., Noviyanti, A.R., dan Janati, D. (2016). Sintesis Silika Metode Sol-Gel sebagai Penyangga Fotokatalis TiO2 terhadap Penurunan Kadar Kromium dan Besi.Jurnal Sains Materi Indonesia. 17(2): 82-89.
Listiani, D., Sapar, A., dan Aritonang, A.B. (2019). Sintesis TiO2-Kaolin dan Uji Aktivitas Fotokatalis untuk Antibakteri Escherichia coli dan Staphylococcus aureus.Indonesian Journal of Pure and Applied Chemistry. 2(3): 130-139.
Fatmawati, D., Aritonang, A.B., dan Nurlina. (2019). Sintesis Dan Karakterisasi TiO2-Kaolin Menggunakan Metode Sol Gel.Jurnal Kimia Khatulistiwa. 8(2).
Fartiwi, R., Warsidah, dan Aritonang, A.B. (2019). Sintesis TiO2/Ti dengan Teknik Anodisasi dan Uji Aktivitas Fotokatalis Sebagai Antibakteri Escherichia coli.Indonesian Journal of Pure and Applied Chemistry. 2(3): 140-148.
Hanaor, D.A.H., Chironi, I., Karatchevtseva, I., Triani, G., and Sorrel, C.C. (2012) Single and Mixed Phase TiO2 Powders Prepared by Excess Hydrolysis of a Titanium Alkoxide.Advances in Applied Ceramics. 111(3):149-158.
Yang, J., Bai, H., Jiang, Q., and Lian, J. (2008). Visible-Light Photocatalysis in Nitrogen-Carbon-Doped TiO2 Films Obtained by Heating TiO2 Gel-Film in an Ionized N2 Gas. The Solid Films. 1736-1742.
Ben-Arfa, B.A., Salvado, I.M., Ferreira, J.M., and Pullar, R.C. (2017). Novel Route for Rapid Sol-Gel Synthesis of Hydroxyapatite, Avoiding Ageing and Using Fast Drying with a 50-Fold ti 200-Fold Reduction in Process Time.Materials Science and Engineering. C, Materials for Biological Application. 70:796-804.
Dong, X., Zhang, F., Hua, C., Rong, C., Zhang, X., Ma, H., Shi, F., Zhang, X., Ma, C., and Xue, M. (2014). Bi-Doped TiO2 with Remarkably Enhanced Photocatalytic Activity Under Simulated Sunlight Induced by Increased Hydrophilicity and Light Absorption Ability.Journal of Advanced Oxidation Technologies. 17(1):39-43.
Prabu, K.M., and Anbarasan, P.M. (2014). Preparation and Characterization of Silver, Magnesium, and Bismuth Doped Titanium Dioxide Nanoparticles for Solar Cell Aplications.International Journal of Science and Research. 3(9): 132-137.
Zhao, H., Pan, F., and Li, Y. (2016). A Review on the Effects of TiO2 Surface Point Defects on CO2 Photoreduction with H2O. Journal of Materiomics.
Alzamly, A., Hamed, F., Ramachandran, T., Bakiro, M., Ahmed, S.H., Mansour, S., Salem, S., Abdul, K., Kaabi, N.S., Meetani, M., and Khaleel, A. (2018). Tunable Band Gap of Bi3+ Doped Anatase TiO2 for Enhanced Photocatalytic Removal of Acetaminophen under UV-Visible Light Irradiation. Journal of Water Reuse and Desalination.
Leontie, L., Caraman, M., Alexe, M., and Harnagea, C. (2002). Structural and Optical Characteristics of Bismuth Oxide Thin Films.Surface Science. 507-510:480-485.
Labib, S. (2015). Preparation; Characterization and Photocatalytic Properties of Doped and Undoped Bi2O3.Journal of Saudi Chemical Society. 11(3):1-9.
Dahlan, A., Wahyuni, S., dan Ansharullah. (2017). Morfologi dan Karakterisasi Pertumbuhan Bakteri Asam Laktat (UM 1.3A)dari Proses Fermentasi Wikau Maombo untuk Studi Awal Produksi Enzim Amilase.Jurnal Sains dan Teknologi Pangan. 2(4):657-663.
Desniar, Setyaningsih, I., Purnama, Y.I. (2016). Penapisan dan Produksi Antibakteri Lactobacillus planetarium NS (9) yang Diisolasi dari Bekasam Ikan Nila Atin.Jurnal Pengolahan Hasil Perikanan Indonesia. 11(2):132-139.
Rosmayanti, dan Yanti, F. (2020). Perhitungan Jumlah Bakteri di Laboratorium Mikrobiologi Menggunakan Pengembangan Metode Spektrofotometri. Jurnal Penelitian Sains. 22(2):76-86.
Gupta K., Singh, R.P., Pandey, A., and Pandey, A. (2013). Photocatalytic Antibacterial Performance of TiO2 and Ag-Doped TiO2 Against S. aureus, P. aeruginosa, and E. coli. Beilstein Journal of Nanotechnology. 4:345-351.
Jong, M., Meijerink, A., Gordon, R.A., Barandiaran, Z., and Seijo, L. (2014). Is Bi2+ Responsible for the Red-Orange Emission of Bismuth-Doped SrB4O7.The Journal of Physical Chemistry. 118: 9696-9705.
Downloads
Published
Issue
Section
License
Copyright (c) 2021 Annisa Furqonita, Anthoni B. Aritonang, M. Agus Wibowo

This work is licensed under a Creative Commons Attribution 4.0 International License.
Authors who publish with this journal agree to the following terms: 1. Authors retain copyright and grant the journal the right of first publication, with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal. 2. Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgement of its initial publication in this journal. 3. Authors are permitted and encouraged to post their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work (see The Effect of Open Access).